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MSDS
MSDS (Material safety Data Sheet)
SECTION1: PRODUCTS & COMPANY IDENTIFICATION
PRODUCT NAME: MAINTENANCE FREE SEALED LEAD ACID RECHARGEABLE BATTERY
MANUFACTURER’S NAME: SHENZHEN NAPEL POWER TECH. CO., LTD.
MANUFACTURER’S ADDRESS: RM. B2504 Fulin international Building, SHENZHEN.CHINA
TELEPHONE NUMBER: +86 755 89330921
FACSIMILE NUMBER:  +86 755 84530030
SECTION 2: HAZARDOUS IDENTIFICATION
COMPONENTS
%WEIGHT
TLV
LD50 ORAL
LC50 INHALATION
LC50 CONTACT
Lead (Pb, PbO2,PbSO4)
About 70%
N/A
(500) mg/Kg
N/A
N/A
Sulfuric Acid
About 20%
1mg/m3
(2.140)mg/Kg
N/A
N/A
Fiberglass Separator
About 5%
N/A
N/A
N/A
N/A
ABS
About 5%
N/A
N/A
N/A
N/A
SECTION3: POSSIBLE HAZARDS
The chemicals mentioned in section2 are contained in a hermetically sealed can risk of exposure occurs only if the battery is mechanically or electrically abused. (See section7 handing & storage),the most likely risk is acute exposure when a cell vents sulfuric acid is irritating to skin and all the other organs. Lead is classified as the heavy metal, if eating without mind will lead toxicities. (See section8 personal protection)
SECTION 4: FIRST AID MEASURES
SULFURIC ACID PRECAUTIONS
SKIN CONTACT:  Flush with water, see doctor if it doesn’t work.
EYE CONTACT:   Flush with water and call doctor immediately.
INGESTION:      Call the doctor and flush mouth with water, have the patient drink milk if patient is conscious. Do not give
                           anything to the unconscious person.
SECTION5: FIREFIGHTING MEASURES
In case of fire in an adjacent area, use water, CO2 or dry chemical extinguishers, if cells are packed in their original containers since the fuel of the fire is basically paper products. For bulk quantities of unpacked cells use LITH-X. In this case, do not use water. as with any fire wear, self-contained breathing apparatus to avoid inhalation of hazardous decomposition products.
SECTION 6: ACCIDENTIAL RELEASE MEASURES
ACTION TAKEN FOR THE LEAKAGE OR SPILLS
If sulfuric acid is spilled from a battery, neutralize the acid with sodium bicarbonate (baking soda), sodium carbon (soda ash), or calcium oxide (lime).Flush the area with water discard to the sewage systems. Do not allow acid into the sewage system before it is neutralized.
WASTE DISPOSAL METHOD:
Neutralized acid may be flushed down the sewer. Used batteries must be treated as hazardous waste and disposed of according to local policy and National Laws. A copy of this material safety data must be supplied to any scrap dealer .
SECTION7: HANDLING & STORAGE
Spill or Leak Procedures:
Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge of unneutralized acid to sewer.
Handling and Storage:
Store batteries in cool, dry, well-ventilated areas with impervious surfaces and adequate containment in the event of spills. Batteries should also be stored under roof for protection against adverse weather conditions. Separate from incompatible materials. Store and handle only in areas with adequate water supply and spill control. Avoid damage to containers. Keep away from fire, sparks and heat.
Precautionary Labeling:
POISON - CAUSES SEVERE BURNS
DANGER - CONTAINS SULFURIC ACID 
SECTION 8: PERSONAL PROTECTION
EXPOSURE
PROTECTION
COMMENTS
SKIN
Rubber gloves, Apron
Protective equipment must be worn if battery is cracked or otherwise damaged.
RESPIRATORY
Respirator (for lead)
A respirator should be worn during reclaim operations if the TLV exceeded.
EYES
Safety goggles, Face Shield
 
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
COMPONENTS
DENSITY
MELTING POINT
SOLLUBILITY (H²O)
ODOR
APPEARANCE
Lead
11.34
327.4°C (Boiling)
None
None
Sliver-Gray Metal
Lead Sulfate
6.2
1070°C (Boiling)
40 mg/l (15°C)
None
White Powder
Lead Dioxide
9.4
290°C (Boiling)
None
None
Brown Powder
Sulfuric Acid
About 1.3
About 114°C (Boiling)
100%
Acidic
Clear Colorless Liquid
Fiberglass Seperator.
N/A
N/A
SLIGHT
TOXIC
WHITE FIBROUS GLASS
ABS
N/A
N/A
NONE
NO ODOR
SOLID
SECTION10: STABILITY & REACTIVITY
COMPONENT
Sulfuric Acid
STABILITY
Stable at all temperatures
POLYMERIZATION
Will not polymarize
INCOMPATIBILITY
Reactive metals, strong bases, most organic compounds
DECOMPOSITION PRODUCTS
Sulfuric dioxide, trioxide, hydrogen sulfide, hydrogen
CONDITIONS TO AVOID
Prohibit smoking, sparks, etc. from battery charging area. Avoid mixing acid with other chemicals.
SECTION11: TOXICOLOGICAL INFORMATION
LEAD: The toxic effects of lead are accumulative and slow to appear. It affects the kidneys, reproductive, and central nervous system.
The symptoms of lead overexposure are anemia, vomiting, headache, stomach pain (lead colic), dizziness, loss of appetite, and muscle and joint pain. Exposure to lead from a battery most often occurs during lead reclaim operations through the breathing or ingestion of lead dusts and fumes.
SULFURIC ACID: Sulfuric acid is a strong corrosive. Contact with acid can cause severe burns on the skin and in the eyes.
Ingestion of sulfuric acid will cause GI tract burns. Acid can be release if the battery case is damaged or if the vents are tampered with.
FIBERGLASS SEPARATOR: Fibrous glass is an irritant of the upper respiratory tract, skin and eyes. Please use the relative protection gears if necessary.
SECTION12: ECOLOGICAL INFORMATION
COMPONENTS
FLASHPOINT
EXPLOSIVE LIMITS
COMMENTS
Lead
None
None
 
Sulfuric Acid
None
None
 
Hydrogen
 
4% - 74.2%
Sealed batteries can emit hydrogen only if over charged(float voltage2.4VPC)
Fiberglass Sep.
N/A
N/A
Poisonous vapors may be released. Please wear self contained breathing apparatus in case of fire.
A B S
None
N/A
Temperatures over 300 °C (572°F) may release combustible gases. Wear positive pressure self contained breathing apparatus.
SECTION13: DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Spent batteries: Send to secondary lead smelter for recycling.
Place neutralized slurry into sealed containers and handle as applicable with state and federal regulations. Large water-diluted spills, after neutralization and testing, should be managed in accordance with approved local, state and federal requirements. Consult state environmental agency and/or federal EPA.
 
SECTION14: Packing & Transportation information
14.1All VRLA batteries must be fully discharged and packaged in a manner as to insure safe handling and conform to all applicable DOT regulations. (49 CFR 173.159d). A dab of silicon caulking or non-conductive tape on each terminal will ensure that no direct shorts occur during shipment.
14.2 VRLA batteries shipments should be made in pallet quantities whenever possible.
14.3 Palletized shipments should be secured with metal bands or poly-wrapped with stack height limited to four (4) feet.
14.4 VRLA batteries shipped on pallets should be of uniform size or be stacked with the larger batteries on the bottom.
14.5 VRLA batteries should be stacked upright in a head-to-base arrangement. Each layer should be separated by cardboard to prevent accidental shorting.
14.6 Smaller quantities of VRLA batteries may be shipped via standard UPS. Be sure that each box does not exceed the UPS weight limit of 70 lbs. A dab of silicon caulking or non-conductive tape on each terminal will ensure that no shorts occur during shipment.
14.7 The outside of every pallet and individual box must be labeled “NON-SPILLABLE” as required by DOT regulations. This label must be visible during transportation.
14.8 As VRLA battery exclude the dangerous goods, can transport by: air, rail, road and water.
14.9 United Nations:      UN NO.         2800
          Packaging           IATA/IACO special provision  A67         For Air Transport
                                            IMDG                    Special Provision 238                              For Sea Transport
14.10 International conventions:
                        Air                   IATA/IACO special provision A67       YES                
                        Sea                 IMDG Special Provision 238                YES
                        Land               ADR(road)                                                YES
                                                 RID (rail)                                                   YES
14.11 Other:            In the USA             Code of Federal Regulations                         (49 CFR Ch. 1 §171-189)
SECTION15: REGULATORY INFORMATION    
Engineering Controls:
Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant.
Work Practices:
Handle batteries cautiously to avoid spills. Make certain vent caps are on securely. Avoid contact with internal components. Wear protective clothing when filling or handling batteries.
Respiratory Protection:
None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection.
Protective gloves:
Rubber or plastic acid-resistant gloves with elbow-length gauntlet.
Eye Protection:
Chemical goggles or face shield.
Other Protection:
Acid-resistant apron. Under severe exposure or emergency conditions, wear acid-resistant clothing and boots.
Emergency Flushing:
In areas where sulfuric acid is handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply
SECTION16: OTHER INFORMATION/DISCLAIMER
This information has been complied from sources considered to be dependable and is to the best of our knowledge and belief, accurate and reliable as of the date complied. However, no representation, warranty (either expressed or implied) or guarantee is made to the accuracy, reliability or completeness of the information contained herein.
This information relates to the specific materials designated and may not be valid for such material used in combination with any other materials or in any process, It is the user’s responsibility to satisfy himself as to the suitability and completeness of this information for his particular use.


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